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织构PNN-PZT陶瓷的光固化成型制备及其电学性能研究 Title:PreparationofPhotocurablePNN-PZTCeramicsbyAdditiveManufacturingandInvestigationofTheirElectricalProperties Abstract: Inrecentyears,thedevelopmentofadvancedmaterialsandmanufacturingtechniqueshasbecomecrucialforvariousindustries.ThisstudyfocusesonthepreparationofPb(Ni1/3Nb2/3)O3-Pb(Zr,Ti)O3(PNN-PZT)ceramicsthroughthemethodofphotocurableadditivemanufacturing.TheprimaryobjectiveistoinvestigatetheelectricalpropertiesofPNN-PZTceramicsfabricatedbythistechnique.Theresearchpresentsacomprehensiveanalysisofthepreparationprocess,followedbyanevaluationoftheelectricalperformanceoftheresultingceramics.ThefindingsindicatethepotentialofphotocurableadditivemanufacturingtoproducePNN-PZTceramicswithenhancedelectricalproperties. 1.Introduction: 1.1Background: PNN-PZTceramicshaveattractedsignificantattentionduetotheirexcellentpiezoelectricandferroelectricproperties.TheconventionalpreparationmethodsofPNN-PZTceramics,suchassolid-statereactionandsol-gel,havelimitationsintermsofcomplexstructurefabricationandhigh-costproduction.Photocurableadditivemanufacturing,apromisingtechniqueinthefieldofadditivemanufacturing,offersapotentialsolutiontothesechallenges. 1.2Objectives: ThisstudyaimstoinvestigatethefeasibilityofutilizingphotocurableadditivemanufacturingforthepreparationofPNN-PZTceramics.Furthermore,theelectricalpropertiesofthefabricatedceramicswillbeexplored,includingpiezoelectricandferroelectricperformance. 2.ExperimentalProcedure: 2.1Materials: Therawmaterials,suchasPbO,NiO,Nb2O5,ZrO2,andTiO2,wereselectedbasedontheirindividualpropertiesandcompatibilityforPNN-PZTceramics. 2.2PreparationProcess: Thephotocurableinkformulationwasdeveloped,consistingofamixtureofprecursorpowders,photoinitiators,andsolvent.Thisinkwasthenloadedintoa3Dprinter,andthelayersofthePNN-PZTceramicstructureswerefabricatedbyalayer-by-layercuringprocessunderUVlight. 2.3SinteringandPost-processing: Aftertheadditivemanufacturingprocess,thegreenbodiesweresubjectedtoasinteringprocesstoachievedens

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