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三段接触氧化—水解酸化工艺处理高浓度感光废水 Title:TreatmentofHigh-ConcentrationPhotosensitiveWastewaterUsingaThree-StepOxidation-HydrolysisAcidificationProcess Abstract: Photosensitivewastewater,generatedfromindustriessuchasprinting,photography,andelectronics,containshighconcentrationsoforganiccompoundsandheavymetals,makingitdifficulttotreatusingconventionalmethods.Thispaperproposesathree-stepoxidation-hydrolysisacidificationprocessasaneffectivetreatmentmethodforhigh-concentrationphotosensitivewastewater.Theprocessinvolvesthreestages:pre-oxidation,hydrolysisacidification,andbiologicaltreatment.Wediscusstheoperationalparameters,efficiency,andcost-effectivenessofthisprocess,highlightingitspotentialforindustrialapplication. 1.Introduction Photosensitivewastewaterischaracterizedbyhighconcentrationsoforganiccompounds,includingphotochemicalagentssuchasdiazocompoundsandheavymetalslikesilverandchromium.Thesecompoundsposesignificantenvironmentalandhealthrisksifnotproperlytreatedbeforedischarge.Conventionaltreatmentprocesses,suchascoagulation,flocculation,andbiologicaltreatment,areoftenineffectiveduetothehighconcentrationandcomplexcompositionofthewastewater.Inthispaper,weproposeathree-stepoxidation-hydrolysisacidificationprocesstoaddressthechallengesassociatedwithtreatinghigh-concentrationphotosensitivewastewater. 2.Three-StepOxidation-HydrolysisAcidificationProcess Thethree-stepprocesscomprisespre-oxidation,hydrolysisacidification,andbiologicaltreatment.Inthepre-oxidationstage,chemicaloxidantslikehydrogenperoxide(H2O2)orozone(O3)areaddedtothewastewatertobreakdowncomplexorganiccompoundsandremovecolor.Thisstepenhancesthesubsequenthydrolysisacidificationandpromotesthebiodegradabilityofthewastewater.ThehydrolysisacidificationstageinvolvesadjustingthepHtoanacidicrange(pH3-5)topromotethereleaseofsolubleorganicmatterandincreasetheefficiencyofsubsequentbiologicaltreatment.Finally,inthebiologicaltreatmentstage,activatedsludgeorotherbiologicalagentsareemployedtofurtherdegradetheorganiccompoundsandreduceth

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