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亚硫酸盐无氰电沉积金新工艺及机制(英文) Title:NovelProcessandMechanismofCyanide-FreeElectrodepositionofGoldusingThiosulfate Abstract: Thetraditionalmethodofgoldelectrodepositioninvolvestheuseoftoxiccyanidecompounds,presentingenvironmentalandsafetyconcerns.Thisstudyaimstoproposeanewprocessforelectrodepositionofgoldusingthiosulfateasacyanide-freealternative.Thiosulfateservesasacomplexingagentforgoldionsandhasthepotentialtobeasafeandenvironmentallyfriendlyalternativeforgoldelectroplating.Inthispaper,wewilldiscussthedevelopmentofthenewprocess,itsmechanism,anditspotentialadvantagesandlimitations. 1.Introduction 1.1Background 1.2Objectives 1.3ScopeoftheStudy 2.ThiosulfateasaCyanide-FreeComplexingAgent 2.1PropertiesofThiosulfate 2.2AdvantagesandLimitationsofThiosulfate 2.3ApplicabilityofThiosulfateinMetalElectroplating 3.GoldElectrodepositionUsingThiosulfate 3.1ExperimentalSetup 3.2ElectrodepositionProcessParameters 3.3ComparisonwithCyanideElectrodepositionProcess 3.4SurfaceMorphologyandMicrostructureofDepositedGoldFilms 4.MechanismofGoldElectrodepositionusingThiosulfate 4.1ThiosulfateasaComplexingAgent 4.2KineticsandThermodynamicsofGoldElectrodeposition 4.3RoleofAdditivesandVariablesintheElectrodepositionProcess 5.AdvantagesofCyanide-FreeGoldElectrodeposition 5.1SafetyandEnvironmentalConsiderations 5.2Cost-Effectiveness 5.3DepositionEfficiencyandQuality 6.PotentialLimitationsandFutureDirections 6.1StabilityandShelf-LifeofThiosulfateSolutions 6.2ControllingtheGrowthMechanismofDepositedGoldFilms 6.3FurtherInvestigationsandOptimization 7.Conclusion 7.1SummaryofFindings 7.2ImplicationsandApplication 7.3FutureProspects References Note:Thisoutlineprovidesageneralstructurefortheresearchpaper.Theactualcontentandsectionswithineachchaptermayvarydependingontheresearchfindingsandtheresearcher'spreferences.

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