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六偏磷酸钠对陶瓷釉料中纳米ZnO分散作用的研究 Title:StudyontheDispersionofNanoscaleZnOinCeramicGlazesbySodiumHexametaphosphate Abstract: NanoscaleZnOhasgainedsignificantattentioninthefieldofceramicglazesduetoitsuniqueoptical,electrical,andantibacterialproperties.However,achievinguniformdispersionofnanoscaleZnOinglazematerialspresentsasignificantchallenge.ThisstudyaimstoinvestigatethedispersioncharacteristicsofnanoscaleZnOinceramicglazesusingsodiumhexametaphosphate(SHMP)asadispersingagent. Introduction: Inrecentyears,nanoscaleZnOhasemergedasapromisingadditiveforceramicglazeformulations.Itspresenceinglazesenhancestheopticalproperties,electricalconductivity,andantimicrobialactivityofthefinalproducts.However,theuniformdispersionofnanoscaleZnOparticleswithinglazematerialsiscrucialforachievingthesedesiredproperties.Sodiumhexametaphosphate(SHMP)hasshownpromiseasadispersingagentfornanoscaleparticlesduetoitsstrongchelatingabilityandabilitytoformstablecomplexes.ThisstudyaimstoinvestigatethedispersionbehaviorofnanoscaleZnOparticlesinceramicglazematerialsusingSHMP. ExperimentalMethod: ThedispersionbehaviorofnanoscaleZnOinglazematerialswasinvestigatedusingacombinationofexperimentaltechniques.Firstly,thenanoscaleZnOparticlesweresynthesizedthroughasol-gelmethod.ThesynthesizednanoparticleswerecharacterizedusingSEM,TEM,andXRDtodeterminetheirmorphology,size,andcrystalstructure.TheglazeformulationswerepreparedwithvaryingpercentagesofnanoscaleZnOandSHMP. ResultsandDiscussion: TheresultsofSEMimagingrevealedthatwithouttheadditionofSHMP,nanoscaleZnOparticlesagglomeratedandformedlargeclusterswithintheglazematrix.However,withtheadditionofSHMP,thedispersionofnanoscaleZnOparticlessignificantlyimproved.SmallerparticlesizesanduniformdispersionwereobservedundertheinfluenceofSHMP,asevidencedbytheSEMandTEMimages. TheXRDanalysisconfirmedthatthecrystalstructureofnanoscaleZnOremainedunaffectedbytheadditionofSHMP.TheXRDpeakscorrespondingtoZnOweresharp,suggestingthepreservationofitscrystalstructurewithintheglazematrix. Thev

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