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固态质子导电器件的研究综述(英文) Title:Areviewofsolid-stateprotonconductingdevices Abstract: Solid-stateprotonconductingdeviceshavegainedsignificantattentioninrecentyearsduetotheirpotentialapplicationsinenergyconversionandstoragedevices.Thispaperprovidesacomprehensivereviewoftheresearchanddevelopmentofsolid-stateprotonconductingdevices,includingthefundamentals,materials,andapplications.Theaimistooutlinethecurrentstate-of-the-artinthisfieldandhighlightthechallengesandfutureprospects. 1.Introduction Thedemandforefficientandsustainableenergyconversionandstoragetechnologieshasfacilitatedtheexplorationofalternativematerialsforelectrolytesindevicessuchasfuelcells,supercapacitors,andsensors.Solid-stateprotonconductingdevices,whichutilizematerialsthatexhibithighprotonconductivityatroomtemperature,haveemergedaspromisingcandidates.Thissectionprovidesanoverviewofthemotivationandsignificanceofsolid-stateprotonconductorsaswellasthepotentialapplications. 2.Fundamentalsofprotonconduction Thissectionfocusesonthefundamentalprinciplesunderlyingprotonconductioninsolid-statematerials.Itdiscussesthemechanismsofprotontransport,suchasGrotthussandvehiclemechanisms,aswellasthefactorsinfluencingprotonconduction,includinghydration,temperature,anddopantconcentration.Theimportanceofoptimizingthesefactorstoenhanceprotonconductivityishighlighted. 3.Solid-stateprotonconductingmaterials Thissectionpresentsacomprehensivereviewofthevariousclassesofsolid-stateprotonconductingmaterials,includingperovskiteoxides,phosphoricacid-dopedpolymers,metal-organicframeworks,andproton-conductingceramics.Itdiscussestheadvantagesandlimitationsofeachmaterialclassandhighlightsrecentresearchadvancementsintheirsynthesisandperformance. 4.Characterizationtechniques Accuratecharacterizationtechniquesarecrucialforunderstandingtheprotonconductionmechanismsanddeterminingtheperformanceofsolid-stateprotonconductingdevices.Thissectionreviewsthecommonlyusedtechniquesformeasuringprotonconductivity,includingimpedancespectroscopy,nuclearmagneticre

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