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湘江流域长沙段有机磷农药在蔬菜中残留及消解动态的研究 Title:ResidueandDissipationDynamicsofOrganophosphorusPesticidesinVegetablesintheChangshaSegmentoftheXiangjiangRiverBasin Abstract: Withthewidespreaduseoforganophosphoruspesticides(OPs)inagriculturalpractices,concernshavebeenraisedregardingtheirresidualpresenceanddissipationdynamicsinvegetables.ThisresearchfocusesonstudyingthelevelsanddissipationpatternsofOPresiduesinvegetablesgrownintheChangshasegmentoftheXiangjiangRiverBasin.Acomprehensiveanalysiswasconductedusingdifferentanalyticaltechniquescombinedwithfieldsurveys. Introduction: Organophosphoruspesticidesarewidelyusedinagricultureduetotheireffectivenessincontrollingpestinfestations.However,theirpersistenceintheenvironment,potentialhealthrisks,andaccumulationinfoodchainshaveraisedconcernsamongconsumersandregulators.Inthisstudy,weaimedtoinvestigatetheresiduelevelsanddissipationdynamicsofOPsinvegetablesgrownintheChangshasegmentoftheXiangjiangRiverBasin,asthisregionplaysasignificantroleinvegetableproduction. Methods: 1.Sampling:RepresentativesamplesofcommonlyconsumedvegetableswerecollectedfromdifferentfarmslocatedintheChangshasegmentoftheXiangjiangRiverBasin. 2.AnalyticalTechniques:TheOPresidueswereanalysedusinggaschromatographycoupledwithmassspectrometry(GC-MS)andliquidchromatographycoupledwithtandemmassspectrometry(LC-MS/MS).Themethodwasvalidatedforaccuracy,precision,andsensitivity. 3.DissipationStudies:ThedissipationofOPsindifferentvegetablesampleswasmonitoredoveraspecifictimeperiodatdefinedintervalsusingavalidatedanalyticalmethod. 4.StatisticalAnalysis:Datawasanalyzedstatisticallyusingappropriatemethodstodetermineresiduelevels,detectionfrequencies,anddissipationpatterns. ResultsandDiscussion: 1.ResidueLevels:TheanalysisofvegetablesamplesrevealedthepresenceofvariousOPresidues.Theconcentrationlevelsvariedaccordingtothetypeofvegetable,withhigherlevelsobservedinleafyvegetablescomparedtorootcrops. 2.DetectionFrequencies:TheoccurrenceofOPresiduesinvegetableswasmonitoredoveraspecifictimeperiod

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